Example for Ann Marie, still working on the edit, but I also have issues capturing a sunset. Link to Ann Marie's post so I wouldn't hijack her thread. Sunset picture, Lake Erie, PA (need help with colors)
This first image is pretty close to how the camera recorded the scene.
This is what I was able to do in Lightroom and now it looks pretty close to what I saw, a bit more dramatic but at least closer.
f/5, ISO 800, 1/60 sec
I tried various settings but nothing came close unless I underexposed the shot. I shot RAW and changed white balance to Cloudy to try and get warmer colors. Edit involved more than just adjusting white balance, everything done in Lightroom.