As per Phil's suggestion; here are the screen shots and workflow of this image. I'll start with the cropped RAW file. I tend to use non-destructive editing techniques so pretty well all my work uses layer masks and adjustment layers:
This is the original image with the offending blue and orange colours, camera right:
Step 1 - I used the pen tool to make a rough selection of the offending area. I stayed inside the woman's head covering by a few pixels. This does not have to be super accurate as the details won't get lost in further processing, they will just get desaturated and tinted. Here is a closeup of part of the selection.
[url=https://flic.kr/p/oasX21]
Step 2 - I made the selection and feathered it slightly ( 5 pixels) and used and a B&W adjustment layer. In this screen shot, you can see, the mask confines the effects to the offending part of the image, and the details of the shawl are still there.
[url=https://flic.kr/p/oataYT]
Step 3 - As I don't want the area to be B&W, I check the tint button on the B&W adjustment layer pop-up. I used the eyedropper tool to take a sample of the colours on the left hand side background of the image. This gets the right hand side into the right colour range.
[url=https://flic.kr/p/oasWWS]
Step 4 - The intensity of the tint is not quite working, so I duplicate this layer two more times to increase the intensity of the layer mask to the point where I am happy with it. I find that her eyebrows are a bit to bright for my liking so I duplicate the base image and set the blending mode to Multiply to darken the image. This is shown here.
[url=https://flic.kr/p/orFrup]
Step 5 - I now apply a black layer mask to hide the the layer and paint on the layer mask with a soft, white brush at around 20% opacity to revel the darker layer in the areas where I have painted. This darkens some of the shiny spots on her face, and unlike the Dodge tool, the layer mask approach is completely reversable and editable.
[url=https://flic.kr/p/orKARL]
Step 6 - I want to draw the viewer's eyes into the image, so I add a vignette. I added an new empty layer to the top of the stack, and with the Elliptical Marquee tool, draw a centred selection that I then invert <Ctrl> <Shft> <I>.
[url=https://flic.kr/p/orFreK]
Step 7 - I click the Refine Edge button on the Elliptical Marquee tool to bring up the pop-up and apply a large feather; in this case, the maximum allowed of 1000 pixels. You need Photoshop PS6 or newer to be able to do this. Older versions of Photoshop limit the amount of feather to a much lower value.
[url=https://flic.kr/p/orFrbD]
Step 8 - I select the Paint Bucket tool, using black, I darken the outside of the frame.
[url=https://flic.kr/p/orKAvW]
Step 9 - This vignette, by itself bleeds into the image, so while still keeping the selection, on the Layers Pallet, I click "Add a Mask" with black as the foreground colour. This significantly reduces the impact of the vignette. I might touch up the mask with a black paint brush to tweak it a bit. I will dial back the intensity of the vignette a bit by reducing the opacity to around 40% or so.
[url=https://flic.kr/p/oau8pa]
Step 10 - I find that the image is a bit too contrastly for my liking (it was taken at a fairly unflattering time of day), so I add one more adjustment layer, just below the vignette in the stack. I use a reversed "S" shape to drop the contrast ever so slightly.
[url=https://flic.kr/p/orXH92]
At this point the image is the way I like it.
[url=https://flic.kr/p/orXH6X]
And finally; a closeup of the layers with descriptions.
[url=https://flic.kr/p/orFqva]
This may seem like a lot of work, but as I stated in a previous posting; the whole thing took me about 2 or 3 minutes....